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World's First Success in Direct and Catalytic Conversion of Nitrogen Gas to Nitrogen-Containing Organic Compounds Under Extremely Mild Conditions at Room Temperature and Atmospheric Pressure

World's First Success in Direct and Catalytic Conversion of Nitrogen Gas to Nitrogen-Containing Organic Compounds Under Extremely Mild Conditions at Room Temperature and Atmospheric Pressure

Oct 26, 2022
World's First Success in Direct and Catalytic Conversion of Nitrogen Gas to Nitrogen-Containing Organic Compounds Under Extremely Mild Conditions at Room Temperature and Atmospheric Pressure

Research groups led by Professor Yoshiaki Nishibayashi from the Graduate School of Engineering at the University of Tokyo, Professor Kazunari Yoshizawa from the Institute for Materials Chemistry and Engineering at Kyushu University, and Professor Hiromasa Tanaka from Daido University have successfully converted nitrogen gas directly and catalytically into cyanate ions (NCO−), a nitrogen-containing compound, under extremely mild reaction conditions at room temperature and atmospheric pressure using the same catalyst used for ammonia synthesis. This is the world's first example of catalytic synthesis of nitrogen-containing organic compounds from nitrogen gas using a molecular catalyst.

Paper Information

Title
Direct synthesis of cyanate anion from dinitrogen catalysed by molybdenum complexes bearing pincer-type ligand
Authors
Takayuki Itabashi, Kazuya Arashiba, Akihito Egi, Hiromasa Tanaka, Keita Sugiyama, Shun Suginome, Shogo Kuriyama, Kazunari Yoshizawa, Yoshiaki Nishibayashi
Journal
Nature Communications
DOI
10.1038/s41467-022-33809-5